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Mass spectra of N-substituted cantharidinimides

✍ Scribed by Pen-Y. Lin; Shaw-T. Lin; David W.-M. Liang

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
116 KB
Volume
39
Category
Article
ISSN
1076-5174

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✦ Synopsis

Abstract

The mass spectra of a series of N‐substituted cantharidinimides were examined. The feature of this series compounds is a sequential double hydrogen transfer from the oxabicycloheptane unit to either the carbonyl group of the succinimide unit or the nitrogen atom of the pyridyl or thiazolyl substituent through space. The ability of the N‐substituent to accept a hydrogen atom possibly leads to the different fragmentation pathway. Copyright Β© 2004 John Wiley & Sons, Ltd.

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