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Mass-spectra of dimethylbicyclo[4.4.0]decane stereoisomers (2,3-; 2,4-; 2,8- and 2,9-dimethylbicyclo[4.4.0]decanes)

โœ Scribed by Ye.S. Brodskii; I.M. Lukashenko; I.A. Musayev; E.Kh. Kurashova; P.I. Sanin

Book ID
116042206
Publisher
Elsevier Science
Year
1977
Weight
531 KB
Volume
17
Category
Article
ISSN
0031-6458

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Thermal unimolecular isomerization of 1,
Thermal unimolecular isomerization of 1,4-dimethylbicyclo[2.2.0]hexane, 1,4-dimethylbicyclo[2.1.1]hexane, and 1,4-dimethylbicyclo[2.1.0]pentane
โœ R. Srinivasan ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 593 KB

The thermal isomerization of the title compounds was studied in the vapor phase. Over the temperature range from 445.1 to 477.5"K7 1,4-dimethylbicyclo[2.2.O]hexane underwent a homogeneous unimolecular reaction to 2,5-dimethyl-175-hexadiene, the rate constants being represented by the equation: k =