Mass spectra of decahydroquinolines
β Scribed by C. K. Yu; Diane Oldfield; D. B. Maclean
- Publisher
- John Wiley and Sons
- Year
- 1970
- Tongue
- English
- Weight
- 496 KB
- Volume
- 4
- Category
- Article
- ISSN
- 1076-5174
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β¦ Synopsis
The mass spectra of cis-and trans-decahydroquinoline, their N-methyl and their Nbenzoyl derivatives have been examined. Several deuterated derivatives of the N-methyl compounds and one C-methyl derivative have been prepared and a study of their spectra has aided in the interpretation of the mechanism of fragmentation. The major fragment ions are formed by loss of two, three and four carbon fragments from the homocyclic ring.
π SIMILAR VOLUMES
The mass spectra are reported for 19 aurones (2-benzylidenecoumaran-3-ones) having a wide variety of functional groups and substitution patterns. The principal ions in these spectra are consistent with the operation of proximity effects demonstrated previously for 6-methoxyaurones.