The formation of ions of the cyclic depsipeptide valinomycin by field desorption has been investigated in detail. The ratio of molecular ions M+' to protonated molecules (M + HI+ has been found to be independent of emitter heating current and the nature of particular additives to the solution. In co
โฆ LIBER โฆ
Mass spectra of cyclic depsipeptides: sporidesmolides
โ Scribed by C.G. Macdonald; J.S. Shannon; A. Taylor
- Publisher
- Elsevier Science
- Year
- 1964
- Tongue
- French
- Weight
- 215 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0040-4039
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## Abstract The synthesis of several 18โmembered cyclodepsipeptides with an alternating sequence of __ฮฑ,ฮฑ__โdisubstituted __ฮฑ__โamino acids and __ฮฑ__โhydroxy acids (compounds **14a**โ**14e**) is described. The ring closure __via__ macrolactonization was accomplished by treatment of a diluted suspen