Marine Bakterien, VII. Enzymatische Bromierung von Pseudilinen und verwandten Heteroarylphenolen mit der Chlorperoxidase ausStreptomyces aureofacens Tü 24
✍ Scribed by Laatsch, Hartmut ;Pudleiner, Heinz ;Pelizaeus, Birgit ;van Pée, Karl-Heinz
- Publisher
- John Wiley and Sons
- Year
- 1994
- Tongue
- English
- Weight
- 651 KB
- Volume
- 1994
- Category
- Article
- ISSN
- 0947-3440
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✦ Synopsis
Marine Bacteria, VII. – Enzymatic Bromination of Pseudilins and Related Heteroarylphenols with a Chloroperoxidase from Streptomyces aureofaciens Tü 24
During the bromination of various substituted synthetic phenyl pyrroles with a chloroperoxidase from Streptomyces aureofaciens Tü 24, mixtures of bromopyrroles are obtained which are not easily accessible by chemical methods. According to the structure of the pyrroles and the kinetics of their transformation, the reaction centre of the enzyme is situated in a slitlike cavity of about 4 × 7 × 8 Ä. magnified image