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Mapping the Potential Energy Surface of the Tolylcarbene Rearrangement in the Inner Phase of a Hemicarcerand

✍ Scribed by Kerdelhué,, Jean-Luc; Langenwalter, Kevin J.; Warmuth, Ralf

Book ID
125504621
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
521 KB
Volume
125
Category
Article
ISSN
0002-7863

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## Abstract The thermal decomposition of six phenyldiazirine (2) hemicarceplexes and the spectroscopic properties of these hemicarceplexes, as well as those of one spiro[cyclobutabenzene‐1(2__H__),3′‐diazirine] (1) and one __p__‐tolyldiazirine (3) hemicarceplex, have been investigated in order to d