Mapping the Influence of Molecular Structure on Rates of Electron Transfer Using Direct Measurements of the Electron Spin−Spin Exchange Interaction
✍ Scribed by Lukas, Aaron S.; Bushard, Patrick J.; Weiss, Emily A.; Wasielewski, Michael R.
- Book ID
- 127249919
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 233 KB
- Volume
- 125
- Category
- Article
- ISSN
- 0002-7863
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📜 SIMILAR VOLUMES
The present work rests on non-adiabatic electron transfer theory. The influence of the molecular dynamics (MD) of exchanging groups on the electron transfer rate is treated. The MD of exchanging groups is described as a stochastic process with two possible states. The transfer between these two stat
The lowest eigenenergies of a few, strongly interacting electrons in a one-dimensional ring are studied in the presence of an impurity barrier. The persistent current I, periodic in an Aharonov-Bohm flux penetrating the ring, is strongly influenced by the electron spin. The impurity does not remove