Abstraet--A calorimetric study was made of micelle formation by a polystyrene-b-polyisoprene block copolymer in n-hexadecane which is a selectively bad solvent for polystyrene. A value of -44.0 + 4.0 kJ mol-~ was obtained for the enthalpy of micellisation, in good agreement with a value of -40.7 +2.
Mapping of carbon nanotubes in the polystyrene domains of a polystyrene-b-polyisoprene-b-polystyrene block copolymer matrix using electrostatic force microscopy
✍ Scribed by Laura Peponi; Agnieszka Tercjak; Junkal Gutierrez; Marta Cardinali; Iñaki Mondragon; Luca Valentini; Josè M. Kenny
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 366 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0008-6223
No coin nor oath required. For personal study only.
✦ Synopsis
Electrostatic force microscopy (EFM) was used to localize and characterize conducting nanofillers inside the domains of a block copolymer matrix. The confinement of carbon nanotubes into polystyrene-b-polyisoprene-b-polystyrene block copolymer (SIS) matrix was investigated. The EFM technique provided information with unprecedented imaging of octadecylamine functionalized single-walled carbon nanotubes, sequestered in the self-assembled lamellar polystyrene domains of the SIS block copolymer matrix.
📜 SIMILAR VOLUMES
The dynamic structure of micelles formed by a polystyrene-b-poly(ethylene/propylene) block copolymer in paraffinic solvents has been studied by electron microscopy, photon correlation spectroscopy and LH and 13C-nuclear magnetic resonance. In n-octane below 50 °, the polystyrene core has two compone