𝔖 Bobbio Scriptorium
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Manual Construction and Mathematics- and Computer-Aided Counting of Stereoisomers. The Example of Oligoinositols.

✍ Scribed by Christoph Ruecker; Ralf Gugisch; Adalbert Kerber


Publisher
John Wiley and Sons
Year
2004
Weight
7 KB
Volume
35
Category
Article
ISSN
0931-7597

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The cyclic hexapeptide cycle[ -Pro'-Gly2-Glu3 (OBzl) -Pro4-Phe5-Leu6-] ( 1 ; OBzl: benzyl ester) was modeled and synthesized to be used as a chiral site for the separation of enantiomers. Total correlation spectroscopy and nuclear Ovehauser effect spectroscopy spectra of the peptide in CDCIB showed