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Mannich-Type Reaction in Water in the Presence of a Surfactant.

✍ Scribed by Junji Itoh; Kohei Fuchibe; Takahiko Akiyama

Publisher
John Wiley and Sons
Year
2007
Weight
28 KB
Volume
38
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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## Abstract Mannich‐type reactions of imines with silicon enolates were found to be catalyzed by neutral salts such as sodium triflate in water as a suspension medium. Unusual kinetic behavior indicates that the presence of the Mannich adduct facilitates the rate of its formation.