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Mannich Condensation of 3,3,5-Trimethylcyclohexanone and Its Oxime

✍ Scribed by S. S. Koval'skaya; N. G. Kozlov; A. V. Tkachev

Book ID: 106523666
Publisher: SP MAIK Nauka/Interperiodica
Year: 2005
Tongue: English
Weight: 239 KB
Volume: 41
Category: Article
ISSN: 1070-4280
DOI: 10.1007/s11178-006-0045-5

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## Abstract Starting from 4‐hydroxycoumarins 4 and 1‐aryl‐2‐(dimethylaminomethyl)prop‐2‐en‐1‐ones 2 the title compounds 6 have been synthesized. The reaction is initiated by addition of the C‐3 carbon atom of 4‐hydroxycoumarin to the enone double bond of the Mannich base, subsequent deamination aff