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Manifestation of the Jahn-Teller active vibrations in the vibronic spectra of tetracoordinate Cu2+, Ni2+ and Zn2+ chlorides

✍ Scribed by N. Trendafilova; G.St. Nikolov; R. Kellner; H. Mikosch; G. Bauer; G. Bogatchev


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
884 KB
Volume
147
Category
Article
ISSN
0301-0104

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The multiple scattering method with local exchange and muff&in potentials is applied to tetrahedral clusters with Cuz+ Ni\*\* , Coz+ and Fez+ as central ions and oxygen and sulphlir as ligands. The calc&ted orbital enerm differences e (t3)'-E(c\*) YC compared to At values deduced from optical spectr