Manganese(III) acetate oxidation of some ketones in the presence of 3-chloropropionic acid and theoretical investigation of the products
✍ Scribed by Akın Akdağ; Okan Tarhan; Lemi Türker
- Book ID
- 114141655
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- English
- Weight
- 137 KB
- Volume
- 571
- Category
- Article
- ISSN
- 0166-1280
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The manganese(III) acetate-catalyzed cycloperoxidation of 4-piperidone-3-carboxylates with 1,1-disubstituted alkenes is described. The 4-piperidone-3-carboxylates reacted with 1,1-disubstituted alkenes in the presence of a catalytic amount of manganese(III) acetate in air at 23°C to give 1-hydroxy-8
The kinetics of oxidation of some neutralized ␣-hydroxy compounds such as glycolic (GA), lactic (LA), ␣-hydroxyisobutyric(IB), mandelic (MA), atrolactic (AL), and benzilic (BA) acids by tetrachloroaurate(III) have been studied. The substrates are oxidized to give formaldehyde, acetaldehyde, acetone,