Manganese(III) Acetate Initiated Oxidative Free Radical Reactions between 2-Amino-1,4-naphthoquinones and β -Dicarbonyl Compounds
✍ Scribed by Jiang, Ming-Chyuan; Chuang, Che-Ping
- Book ID
- 121504208
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 62 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0022-3263
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The manganese(III) initiated oxidative free radical reaction between 1,4-naphthoquinones and o~-alkylmalonates is described. Benzo[a]anthraquinones, benzo[f]indole-4,9-diones and naphtho [2,3-b] furan-4,9-diones can be prepared effectively from readily available 1,4-naphthoquinones and ~alkylmalonat
Absbuctz The manganese(ll1) initiated oxidadve free mlical reaction between 1,4-nqhthoquinme and a-bemyl makmtes giving benzo[alanthmpinones is descriW. Recently, there has been a growing interest in the application of free radical cyclization reactions to the formation of ring systems.1 Benz.o[a]a