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Manganese(III) acetate and copper(II) acetate promoted oxidation of β-enaminoamides and β-enaminoesters

✍ Scribed by Janine Cossy; Abderrahim Bouzide


Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
594 KB
Volume
55
Category
Article
ISSN
0040-4020

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Kinetics and mechanism of oxidation ofα,
✍ S. Pulla Rao; M. Anand Rao 📂 Article 📅 1993 🏛 Springer 🌐 English ⚖ 329 KB

The kinetics of oxidation of c~,/?-unsaturated alcohols (UA's), such as prop-2-ene-l-ol, but-2-ene-l-ol and 3phenyl-prop-2-ene-l-ol, by manganese(III) acetate in aqueous H2SO 4 at constant ionic strength and different acidities has been studied. The reaction was found to proceed through an outer sph