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Manganese triacetate mediated regeneration of carbonyl compounds from oximes

โœ Scribed by Ayhan S. Demir; Cihangir Tanyeli; Ertan Altinel

Book ID
104258004
Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
147 KB
Volume
38
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

A new method for the direct conversion of oximes into aldehydes and ketones by treatment with manganese triacetate is described. Manganese triacetate can be used for an effective and mild oxidizing agent for the regeneration of carbonyl compounds from oximes in good yield. Many functional groups are tolerated under the reaction conditions.

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## Abstract For Abstract see ChemInform Abstract in Full Text.

Regeneration of carbonyl compounds from
Regeneration of carbonyl compounds from oximes under microwave irradiations
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A new and efficient method for the cleavage of oximes l has been achieved by a simple reaction ofa ketoxime or an aldoxime with bismuth trichloride in tetrahydrofuran under microwave irradiations.