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Manganese dioxide oxidation of hydroxylamines to nitrones

โœ Scribed by Stefano Cicchi; Marco Marradi; Andrea Goti; Alberto Brandi

Book ID
104231279
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
62 KB
Volume
42
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Several structurally differentiated N,N-dialkylhydroxylamines were oxidised to the corresponding nitrones using MnO 2 . Manganese dioxide revealed an efficient and mild reagent for oxidation of hydroxylamines, showing a level of regioselectivity comparable to HgO. Its non-toxicity makes MnO 2 the reagent of choice for replacing HgO in this oxidation.

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