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Manganese Complexes of 1,3,5-Triaza-7-phosphaadamantane (PTA): The First Nitrogen-Bound Transition-Metal Complex of PTA

✍ Scribed by Frost, Brian J.; Bautista, Carolyn M.; Huang, Rongcai; Shearer, Jason

Book ID: 125959345
Publisher: American Chemical Society
Year: 2006
Tongue: English
Weight: 98 KB
Volume: 45
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic060322p

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## Abstract Addition of BH~3~ to 1,3,5‐triaza‐7‐phosphaadamantane (PTA) leads to the formation of the first coordination complex of PTA in which a nitrogen and not the phosphorus of PTA is involved in the bonding. Multinuclear NMR spectroscopy, X‐ray crystallography, and computational chemistry are