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Manganese chloride-catalyzed cross-coupling and carbonylative cross-coupling of organostannanes with iodonium salts

✍ Scribed by Suk-Ku Kang; Won-Yeob Kim; Yong-Tack Lee; Sung-Ki Ahn; Jin-Chul Kim

Book ID
104258869
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
118 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis

The MnCleΒ°4H20-catalyzed cross-coupling and carbonvlative cross-coupling of organostannanes with hypervalent iodonium salts afforded biaryls and biaryl ketones, respectively.

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Cross-coupling and carbonylative cross-coupling of organofluorosilanes with hypervalent iodonium tetrafluoroborates
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The palladium-catalyzed cross-coupling and carbonylative cross-coupling of aryl-, alkenyl-, and alkynylfluorosilanes promoted by fluoride ion with hypervalent aryl-, alkenyliodonium tetrafluoroborates were achieved at room temperature under an atmospheric pressure of carbon monoxide.