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Main Group Lewis Acid/Base-Stabilised Phosphanylboranes

โœ Scribed by Ariane Adolf; Manfred Zabel; Manfred Scheer

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
203 KB
Volume
2007
Category
Article
ISSN
1434-1948

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## Abstract Quantumโ€chemical calculations with DFT (BP86) and ab initio methods (MP2, SCSโ€MP2) were carried out for protonated and diprotonated compounds Nโ€H^+^ and Nโ€(H^+^)~2~ and for the complexes Nโ€BH~3~, Nโ€(BH~3~)~2~, Nโ€CO~2~, Nโ€(CO~2~)~2~, Nโ€W(CO)~5~, Nโ€Ni(CO)~3~ and Nโ€Ni(CO)~2~ where N=C(PH~3