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Main-Chain Ionic Chiral Polymers: Synthesis of Optically Active Quaternary Ammonium Sulfonate Polymers and Their Application in Asymmetric Catalysis

โœ Scribed by Itsuno, Shinichi; Paul, Devproshad K.; Salam, M. A.; Haraguchi, Naoki


Book ID
120305172
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
158 KB
Volume
132
Category
Article
ISSN
0002-7863

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Synthesis of optically active polymers w
โœ Qiao-Sheng Hu; Chaode Sun; Colleen E Monaghan ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 70 KB

Optically active ephedrine-bearing poly(phenylene)s have been synthesized by using the Suzuki coupling polymerization. Their application as polymeric chiral catalysts for asymmetric addition of diethylzinc to aldehydes has been studied and good enantioselectivity was observed. The strategy to synthe