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Magnitudes and relative sign of J(119Sn,13C) and J(119Sn,H) coupling constants in some vinyltin(IV) compounds obtained by 2D NMR spectroscopy

✍ Scribed by Antonín Lyčka; Ivan Tkáč; Jaroslav Holeček; Vladimír Pejchal


Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
232 KB
Volume
32
Category
Article
ISSN
0749-1581

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✦ Synopsis


Abstract

Two‐dimensional H,C‐COSY spectra of some vinyltin(IV) compounds were measured. The relative signs of ^n^J(^119^Sn, ^13^C) and __^(n+1)^__J(^119^Sn, ^1^H) coupling constants were determined after analysis of the orientation of appropriate ^119/117^Sn satellites in H,C‐COSY spectra.


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Magnitudes and relative signs of J(119Sn
✍ Antonín Lyčka; Josef Jirman; Jaroslav Holeček 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 317 KB

## Abstract Two‐dimensional H,C‐COSY spectra of some tetra‐, penta‐ and hexa‐coordinated organotin(IV) compounds were measured. The relative signs of ^__n__^__J__(^119^Sn,^13^C) and (^__n__+1^ __J__(^119^Sn,^1^H) coupling constants were determined after analysis of the orientation of the appropriat