The c-axis thermal expansion coefficient of SbCL-GIG i$ obtained from analysis of COO/) X-ray diffractograms for stages l-3. A decrease in thermal expansion coefficient with increasing stage is observed and it is related to a higher charge transfer for the higher stages than for the lower ones. The
Magnetostriction of pristine graphite and SbCl5-graphite intercalation compounds
β Scribed by Y. Yosida; S. Tanuma
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 493 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0008-6223
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β¦ Synopsis
Magnetostrictive strain in pristine highly oriented pyrolytic graphite (HOPG) and SbCI,-graphite intercalation compounds (GIG's) has been studied in steady magnetic fields up to IO tesla, including the quantum oscillation effect. Fourier spectra of the magneto-oscillations are stage dependent and in agreement with those reported by Takahashi et a/. For pristine HOPG, the monotonic component of the longitudinal magnetostrictive strain (LMS) parallel to the c-axis is found to be negative and to increase in magnitude with increasing width at half maximum intensity of the (002) line of X-ray diffraction. This result is explained qualitatively within the framework of the Keyes theory by considering the reduction of the static shear modulus of graphite due to the displacement of basal-plane dislocations. The stress coefficient of the majority hole Fermi surface is determined as a In S,/I?U,,,, = 0.034 + 0.006 kbar-' by using magnetostriction and torque de Haas-van Alphen measurements.
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