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Magneto-Structural Characterization of Metallocene-Bridged Nitronyl Nitroxide Diradicals by X-Ray, Magnetic Measurements, Solid-state NMR Spectroscopy, and Ab Initio Calculations

✍ Scribed by Christian Sporer; Henrike Heise; Klaus Wurst; Daniel Ruiz-Molina; Holger Kopacka; Peter Jaitner; Frank Köhler; Juan J. Novoa; Jaume Veciana


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
23 KB
Volume
10
Category
Article
ISSN
0947-6539

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Magneto-Structural Characterization of M
✍ Christian Sporer; Henrike Heise; Klaus Wurst; Daniel Ruiz-Molina; Holger Kopacka 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 324 KB 👁 1 views

## Abstract Crystallization of ferrocene and ruthenocene substituted in the 1‐ and 1′‐positions by two nitronyl nitroxide radicals gave the new crystal phases β‐**1** (besides the known phase α‐**1**), α‐**2**, and β‐**2** whose structures were determined by X‐ray analysis. In β‐**1** the radical m