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Magnetism and 151 Eu Mössbauer Spectra of α- and β-Eu2GeS4

✍ Scribed by Markus Tampier; Dirk Johrendt; Rainer Pöttgen; Gunter Kotzyba; Henning Trill; Bernd D. Mosel


Publisher
John Wiley and Sons
Year
2002
Tongue
German
Weight
118 KB
Volume
628
Category
Article
ISSN
0372-7874

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Single-phase samples of REAgMg (RE ‫؍‬ La, Ce, Eu, Yb) and EuAuMg were prepared by reacting the elements in sealed tantalum tubes in a high-frequency furnace. LaAgMg and CeAgMg adopt the hexagonal ZrNiAl-type structure, while EuAgMg, YbAgMg, and EuAuMg crystallize with the orthorhombic TiNiSi type.

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The title compounds were investigated by magnetic susceptibility measurements and 151 Eu Mo¨ssbauer spectroscopy. EuZnIn and EuPtIn show Curie-Weiss behavior above 60 K with experimental magnetic moments of 7.80(5) and 8.0(1) B / Eu, respectively, indicating divalent europium. The zinc compound orde