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Magnetic, transport and electronic structure properties of U2RuGa8

✍ Scribed by R. Troć; Z. Bukowski; C. Sułkowski; J.A. Morkowski; A. Szajek; G. Chełkowska


Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
374 KB
Volume
359-361
Category
Article
ISSN
0921-4526

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✦ Synopsis


A single crystal of uranium ternary intermetallic of U 2 RuGa 8 was grown by the Ga self-flux method. This compound crystallizes in the tetragonal unit cell of space group P4/mmm. Despite the fairly large U-U shortest distance of 4.22 A ˚, this compound shows no signs of any magnetic ordering down to 1.9 K. Instead, the susceptibility measured along the a and c axes, goes through a broad maximum at T max ¼ 220 K showing a distinct anisotropy. For j||a there is a weak temperature dependence of the electrical resistivity with a large value of r 0 ¼ 117 mO cm; while for j||c the rðTÞ curve goes through a maximum at about 130 K. The magnetoresistivity measured along two crystallographic directions is small and positive. The thermopower S for the two directions studied is positive and larger along the a-axis. It goes through a broad maximum at 175 K reaching a value of 45 mV/K. The electronic structure has been calculated by the tight-binding linear muffin-tin orbital method (TB-LMTO) and the results were used in calculation of the valence band near the Fermi level compared next to that found in photoemission experiment. The core 4f spectra are also presented. All the above properties are discussed in view of mixed valence behaviour of uranium atom in this compound.


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