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Magnetic relaxation in cyanide based single molecule magnets

✍ Scribed by S.I. Klokishner; S.M. Ostrovsky; A.V. Palii; K. Dunbar

Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
248 KB
Volume
838
Category
Article
ISSN
0022-2860

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A cyclic complex [Ni(12)(chp)(12)(O(2)CMe)(12)(thf)(6)(H(2)O)(6)] (1) has been synthesised and studied (chp=6-chloro-2-pyridonate). Complex 1 exhibits ferromagnetic exchange between the S=1 centres, giving an S=12 spin ground state. Detailed studies demonstrate that it is a single-molecule magnet wi