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Magnetic properties of trinuclear nickel complexes-building blocks of single-molecule magnets

✍ Scribed by A. V. Klimov; V. L. Berdinskii

Book ID
111647581
Publisher
SP MAIK Nauka/Interperiodica
Year
2012
Tongue
English
Weight
316 KB
Volume
57
Category
Article
ISSN
0036-0236

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A cyclic complex [Ni(12)(chp)(12)(O(2)CMe)(12)(thf)(6)(H(2)O)(6)] (1) has been synthesised and studied (chp=6-chloro-2-pyridonate). Complex 1 exhibits ferromagnetic exchange between the S=1 centres, giving an S=12 spin ground state. Detailed studies demonstrate that it is a single-molecule magnet wi