## Abstract For Abstract see ChemInform Abstract in Full Text.
Magnetic phase transitions in (Nd, Dy)Co2 and (Pr, Dy)Co2 compounds
β Scribed by N.H. Duc; P.E. Brommer; J.J.M. Franse
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 515 KB
- Volume
- 191
- Category
- Article
- ISSN
- 0921-4526
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β¦ Synopsis
In a series of (Nd, Dy)Co 2 and (Pr, Dy)Co 2 compounds, the type of the magnetic phase transition was studied by magnetization and electrical-resisitivity measurements. In both systems, a change of type was observed from second order (for NdCo 2 and PrC02) to first order (for compounds containing more than about 20% Dy). The results are discussed in the Inoue-Shimizu model, generalized in such a way that the presence of both light and heavy rare-earth atoms is taken into account. The volume dependence of the parameter a 3 (i.e. of the free-energy contribution a3M2co/4) is supposed to play a decisive role in the determination of the order of the magnetic transition.
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