Magnetic ordering in [Ni en3] (NO3)2
β Scribed by A.J. Van Duyneveldt; A. Van Der Bilt; J.P.C. Vreugdenhil; R.L. Carlin
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- English
- Weight
- 178 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The zero-field susceptibility of [Ni e.ns](NO$z indicates that this compound orders antiferromagnetically at 1.30'K. Part of the H-Tphase diagram is also presented. * -On leave from the Dejwtment of Ci&&try, University of. Illinois at Chica& Circle, Chicago,IlRnois 6068& USA.
π SIMILAR VOLUMES
## Abstract The oxidation of copper, zinc and nickel by N~2~O~5~ led, respectively, to turquoiseβcoloured single crystals of (NO)Cu(NO~3~)~3~ [monoclinic, __P__2~1~/__m__, __Z__ = 2, __a__ = 465.90(5), __b__ = 1111.7(1), __c__ = 700.7(1) pm, __Ξ²__ = 100.70(2)Β°, __wR__~2~ = 0.0566], lightβyellow sin
Metal Oxidation with N 2 O 5 : The Nitrosylium Nitrates (NO)Cu(NO 3 ) 3 , (NO)2[Zn(NO3)4] and (NO)6[Ni4(NO3)12](NO3)2β’(HNO3). -N2O5 is prepared by reaction of fuming HNO3 with P4O10 and directly condensed on the metal powders. The crystal structures of the resulting title compounds are determined by