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Magnetic interactions in Mn(II)—methylpyrazole complexes

✍ Scribed by Reinhard Stösser; Regina Kalähne; Klaus Möckel; Eveline Backhaus


Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
478 KB
Volume
195
Category
Article
ISSN
0022-2860

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Apoconalbumin binds \_Mn(II) at two sites with association constants of K1 = 7(%1) x lo4 and Kz = 0.4(?0.25) x lo4 M-l. The binding is tighter in the presence of excess bicarbonate resulting in K1 = l-8(\*0.2) X lo5 and K2 = 3(+2) X IO4 M-l. The electron paramagnetic resonance spectrum (at both 9 an