✦ LIBER ✦

Magnetic field effects on the fluorescence of intramolecular electron-donor-acceptor systems

✍ Scribed by Yoshifumi Tanimoto; Natsuo Okada; Michiya Itoh; Kaoru Iwai; Kayoko Sugioka; Fukuo Takemura; Ryoichi Nakagaki; Saburo Nagakura

Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 465 KB
Volume: 136
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(87)87295-0

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✦ Synopsis

The external magnetic field effects on the exciplex fluorescence of a-( 4-dimethylaminophenyI)-o-( 9-phenanthryl)alkanes have been studied by photostationary, time-resolved, and magnetic field modulation fluorescence spectroscopy. The singlet-triplet degeneracy of the radical ion pair is suggested to occur at a methylene chain length of about ten.

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