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Magnetic field effect on monophotonic ionization of N,N,N′,N′-tetramethylbenzidine in propionitrile and n-butyronitrile

✍ Scribed by Toshiro Saito; Yoshinori Hirata; Noboru Mataga


Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
407 KB
Volume
145
Category
Article
ISSN
0009-2614

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✦ Synopsis


The magnetic field effect on the monophotonic ionization of N,N,N',N'-tetramethylbenzidine (TBM) in propionitrile and nbutyronitrile has been studied by microsecond transient absorption measurements. The structure of the initially formed ion pair which recombines to form the triplet state of TMB and the mechanism of the photoionization process are discussed.


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