Magnetic field effects on the photoionization yield of N.N,N',N'-tetramethyl-p-phenylenediamine in deaerated 2-propanol have been studied by transient photoconductivity measurements. The photocurrent increases by about 15% in the presence of a magnetic field (720 mT). The results are interpreted in
Magnetic field effect on monophotonic ionization of N,N,N′,N′-tetramethylbenzidine in propionitrile and n-butyronitrile
✍ Scribed by Toshiro Saito; Yoshinori Hirata; Noboru Mataga
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 407 KB
- Volume
- 145
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
The magnetic field effect on the monophotonic ionization of N,N,N',N'-tetramethylbenzidine (TBM) in propionitrile and nbutyronitrile has been studied by microsecond transient absorption measurements. The structure of the initially formed ion pair which recombines to form the triplet state of TMB and the mechanism of the photoionization process are discussed.
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