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Magnetic field dependence of the spin—spin relaxation time of ferric ions in Fe(NO3)3·9H2O and in frozen aqueous solutions

✍ Scribed by S. Mørup; N. Thrane


Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
418 KB
Volume
21
Category
Article
ISSN
0009-2614

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✦ Synopsis


The electronic relaxation of ferric ions in Fe(N03)3'9H20 and in frozen aqueous mlutions has been invest@ted by use of hlijssbsuer spectroscopy. The application of an external magnetic field causes a pronounced tiaease of the spin-s-pin relaxation time, an effect which is contrary to that normally found in ferric compounds. An explanation is given bared on a difFerence in the ionic state energies of neighbouring ions induced by the applied magnetic field.


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Magnetic-Field-Dependent Electronic Rela
✍ D. Hugh Powell; André E. Merbach; Gabriel González; Ernö Brücher; Károly Micskei 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 German ⚖ 823 KB

## Abstract EPR Spectra have been measured for aqueous solutions of a series of Gd^3+^ complexes at variable temperature and a range of magnetic fields; S‐band (0.14 T), X‐band (0.34 T), Q‐band (1.2 T), and 2‐mm‐band (5.0 T). The major contribution to the observed line widths is magnetic‐field‐depe