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Magnetic Exchange between Orbitally Degenerate Ions: A New Development for the Effective Hamiltonian

✍ Scribed by Borrás-Almenar, J. J.; Clemente-Juan, J. M.; Coronado, E.; Palii, A. V.; Tsukerblat, B. S.

Book ID
127313267
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
361 KB
Volume
102
Category
Article
ISSN
1089-5639

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Magnetic Exchange between Orbitally Dege
Magnetic Exchange between Orbitally Degenerate Metal Ions: The Problem of Magnetic Anisotropy
✍ J.J. Borrás-Almenar; E. Coronado; J.M. Clemente-Juan; A.V. Palii; B.S. Tsukerbla 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 545 KB

In this paper we show that a strong magnetic anisotropy appears in exchange mixed+valence clusters containing orbitally degenerate metal ions. Combining an e4ective Hamiltonian approach with the technique of the irreducible tensor operators (ITO) and pseudoangular momentum representation we have sol