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Magnetic Coupling in End-to-End Azido-Bridged Copper and Nickel Binuclear Complexes: A Theoretical Study

✍ Scribed by Fabrizi de Biani, Fabrizia; Ruiz, Eliseo; Cano, Joan; Novoa, Juan J.; Alvarez, Santiago

Book ID: 120637579
Publisher: American Chemical Society
Year: 2000
Tongue: English
Weight: 238 KB
Volume: 39
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic000005x

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## Abstract A new end‐to‐end azido double‐bridged copper(II) complex [Cu~2~L~2~(N~3~)~2~] (1) was synthesized and characterized (L=1,1,1‐trifluoro‐7‐(dimethylamino)‐4‐methyl‐5‐aza‐3‐hepten‐2‐onato). Despite the rather long CuCu distance (5.105(1) Å), the magnetic interaction is ferromagnetic with