✦ LIBER ✦
Magnetic Circular Dichroism of the Long-Wavelength π-π* Transitions in Nitrogen-Containing Heteroconjugated Aromatic Compounds and in Selected Ruthenium Complexes
✍ Scribed by Peter Kleindienst; Peter Belser; Georges H. Wagnière
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- German
- Weight
- 222 KB
- Volume
- 86
- Category
- Article
- ISSN
- 0018-019X
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✦ Synopsis
Abstract
The long‐wavelength magnetic circular dichroism (MCD) spectra of some nitrogen‐containing heteroconjugated aromatic compounds have been recorded and interpreted on the basis of quantum‐chemical model calculations. In particular, the dependence of the MCD bands on the positions of the N‐atoms inside the aromatic rings and on substituents has been investigated.
Some of the compounds considered form Ru^2+^ complexes. The influence of complexation on the long‐wavelength π‐π* bands of the ligands has also been recorded and discussed.