Magnetic circular dichroism of non-heme iron proteins
โ Scribed by D.D. Ulmer; B. Holmquist; B.L. Vallee
- Book ID
- 118853708
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- English
- Weight
- 434 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0006-291X
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The nature of the ethyl isocyanide compbxes of fen-i-and ferroheme was investigated iu terms of the magnetic circular dichroism @ICD) spectroscopy. The complex formation of heme with ethyl isocyanide was criticalIy dependent on the solvent system, thus, on structures of heme before addition of the I
The magnetic circular dichroism (hKD) spectra for Fe'+ and Fe'+ protoporphyrins (hemin and heme) with and without pyridine have revealed the sensitivity of the electronic structures of the complexes ABSTRACT formed to the solvent system: (1) The hemin in au aqueous ethylene glycol solution gave the