A semi-mncroscopic theory of optical circular blrefrinpnce (OCB) in abitrary dense optically active bodies is propod, comprising in 3 concise tensorial formalism the electromagnetic multipolar ~olarizabilities of all orders. Besides spatial dispersion of arbitrary order, frequency dispersion 2nd nbs
Magnetic circular dichroism of molecules in dense media: Dimerization of benzoic acids
β Scribed by Y.H. Yoon; S.T. Lee; D.J. Shieh; H. Eyring; S.H. Lin
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 315 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
Kcscivcd 10 UcI~rber 1975 The purpose of this communic~tian hz~s been to show the application of MCI) to dimcrization of bcnzoic acid and its detivativcs. We present results of the dimcrization equilibrium constants from rcsolvinp the obsavccl MCI> spectra of the intramolwular charge transfer band (CT) into the spectra of monumcrs and dimcrs, and of the B-coefficients (or the msgnctic rotational strcnghs) of :hc CT band Of MCD of ~r~onomers and dimers.
π SIMILAR VOLUMES
Magnetic circular dichroism of trapped electrons in frozen matrices has been observed fcr the first time. It is concluded that the excited state of trapped elecrrons solvaied by water molec;ulcs at 77 K Inas orbital angular momentum whereas that of electrons solvatcd by ethanol molecules at 77 K dae