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Magnetic circular dichroism and the Jahn-Teller effect in the potassium atom “blue triplet” in krypton and xenon matrices

✍ Scribed by Cindy Samet; Janna L. Rose; Paul N. Schatz; M.C.M. O'Brien

Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
475 KB
Volume
159
Category
Article
ISSN
0009-2614

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Magnetic circular dichroism of the potas
Magnetic circular dichroism of the potassium atom “blue triplet” in a xenon matrix
✍ Cindy Samet; Janna L. Rose; Bryce E. Williamson; Paul N. Schatz 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 473 KB

The WXe "blue triplet" spectrum (730-790 nm) arises from K atoms in three distinct sites. Each site gives rise to a similar 'S-+\*P triplet pattern. The effective excited state spin-orbit coupling constant is -170 cm-' compared to the values -213 and -196 cm-' for NaIXe and Li/Xe respectively.