𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Magnetic and spectroscopic properties of copper(II) complexes with 1-salicoyl-4-phenylthiosemicarbazide

✍ Scribed by Narayan T. Akinchan; Douglas X. West; Yong Yang; Michelle M. Salberg; Tracey L. Klein

Publisher
Springer
Year
1995
Tongue
English
Weight
394 KB
Volume
20
Category
Article
ISSN
0340-4285

No coin nor oath required. For personal study only.

✦ Synopsis

CU II complexes of 1-salicoyl-4-phenylthiosemicarbazide (SPT) have been synthesized and characterized by means of elemental analysis, magnetic measurements, and i.r. and e.p.r, spectroscopic methods; 1H-and 13C-n.m.r. and mass spectral data on the thiosemicarbazide are also reported. A paramagnetic complex #elf= 1.298B.M., is formed with copper(II) sulphate; the low magnetic moment and the e.p.r, spectral data suggest a binuclear species. A diamagnetic complex due to a strong Cu-Cu interaction has been isolated with copper(II) chloride.

πŸ“œ SIMILAR VOLUMES

Magnetic and spectroscopic investigation
Magnetic and spectroscopic investigations of tetra(4-t-butyl)phthalocyano complexes of cobalt(II) andΒ­copper(II)
✍ Reimar Heucher; G. V. R. Chanramouli; Periakaruppan T. Manoharan πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 114 KB πŸ‘ 2 views

The tetra(4-t-butyl)phthalocyanine derivatives of Co and Cu have been studied by ESR spectroscopy in solution owing to their solubility in polar and non-polar solvents. The cobalt complex gives a well-resolved EPR spectrum in toluene glass at 77 K with g k = 2.018, g c = 2.785, A k = 0.0155 cm Γ€1 ,