Magnetic and spectral properties of oxovanadium(IV) complexes of schiff bases derived from halo-substituted salicylaldehyde and aniline
โ Scribed by A. Syamal; K.S. Kale
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 538 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0022-2860
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Reaction of copper(lll ions with the Schiff bases derived from histamine and salicylaldehyde or 2pyridinecarbaldehyde were investigated in acidic and basic media. The copper complexes obtained from the reactions in acidic solutions were mononuclear complexes I and II, while those from the reactions
Light brown [VO(5-NO 2 salen)] ' 2H 2 O (1; H 2 (5-NO 2 salen)โซุโฌN, N-di-5-nitrosalicylidene-1,2-ethanediamine) and orange [VO(5-NO 2 sal-meso-stien)] ' 0.5H 2 O (2; H 2 (5-NO 2 salmeso-stien) โซุโฌ N,N-di-5-nitrosalicylidene-(R,S)(S,R)-1,2diphenyl-1,2-ethanediamine) which have linear chain structures