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Magnetic and NIR-spectroscopic studies on mixed-valent Fe(II)/Fe(III)- compounds

✍ Scribed by W. Haase; P. Fleischhauer; R. Werner; M. Behlendorf; J. Ensling; S.K. Dutta; K. Nag


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
62 KB
Volume
59
Category
Article
ISSN
0162-0134

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Apoconalbumin binds \_Mn(II) at two sites with association constants of K1 = 7(%1) x lo4 and Kz = 0.4(?0.25) x lo4 M-l. The binding is tighter in the presence of excess bicarbonate resulting in K1 = l-8(\*0.2) X lo5 and K2 = 3(+2) X IO4 M-l. The electron paramagnetic resonance spectrum (at both 9 an