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Magnesium(II) Complexes of the dpp-BIAN Radical-Anion: Synthesis, Molecular Structure, and Catalytic Activity in Lactide Polymerization

✍ Scribed by Igor L. Fedushkin; Alexander G. Morozov; Valentina A. Chudakova; Georgy K. Fukin; Vladimir K. Cherkasov


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
281 KB
Volume
2009
Category
Article
ISSN
1434-1948

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✍ Christoph Schlünken; Miguel A. Esteruelas; Fernando J. Lahoz; Luis A. Oro; Helmu 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 234 KB 👁 1 views

## Abstract The five‐coordinate compounds [MHCl(CO)(P__i__Pr~3~)~2~] (where 1a: M = Ru; 1b: M = Os) react with P__i__Pr~2~R\* [where R\* = CH(Me)Ph] to give the octahedral complexes __mer__‐[MHCl(CO)(P__i__Pr~2~R\*)~3~] (6 and 7). The lability of the phosphane __trans__ to the hydride is illustrate