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Magnesium chloride supported catalysts for olefin polymerization. XIX. Titanium oxidation states, catalyst deactivation, and active site structure

✍ Scribed by James C. W. Chien; Siegfried Weber; Youliang Hu


Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
880 KB
Volume
27
Category
Article
ISSN
0887-624X

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Ziegler–Natta MgCl2-supported catalysts:
✍ Daniele Fregonese; Stefano Mortara; Silvano Bresadola πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 English βš– 147 KB

The chemical interaction between the procatalyst MgCl 2 /TiCl 4 /EB (EB = ethylbenzoate) and the cocatalyst triethylaluminium was investigated with the purpose to find a relationship between the degree of titanium reduction and the catalytic activity in ethene and propene polymerizations. This inter