Magnesium cation-perturbed charge-transfer interactions
β Scribed by Maurizio Cignitti; Laura Soccorsi
- Book ID
- 108323681
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 149 KB
- Volume
- 138
- Category
- Article
- ISSN
- 0020-1693
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## Abstract We performed __ab initio__ pseudopotential and CNDO calculations on Ξ³βaminobutyric acid (GABA) and its Ca^2+^ and Mg^2+^ clathrates. We were particularly interested in the rotational barrier existing between two extreme conformers of GABA and its modification upon metal complexing. We f
THE tropylium ion I is an, interesting acceptor in charge-transfer complex formation, and we recently reported the formation of such complexes with aromatic hydrocarbons. 2 For tropylium iodide a charge-transfer band at 575 m in methylene chloride has been observed by Harmon and coworkers.3 In com