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Magnesiation of Isodicyclopentadiene. Formation of Sandwich and Monomeric Complexes and the Stereoselectivity of Their Reactions with Transition Metal Halides

✍ Scribed by Gobley, Olivier; Gentil, Sébastien; Schloss, Jeffrey D.; Rogers, Robin D.; Gallucci, Judith C.; Meunier, Philippe; Gautheron, Bernard; Paquette, Leo A.

Book ID: 127340260
Publisher: American Chemical Society
Year: 1999
Tongue: English
Weight: 71 KB
Volume: 18
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om990200n

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## Abstract The synthesis of cobalt(III) complexes with the new linear pentadentate ligands meso‐ and racemic 2,6‐bis(3__S__)‐3‐carboxy‐4‐methyl‐2‐azapentylpyridine (**2**) are described. Only one of the different possible isomers is obtained from each ligand. The structure of the complexes has bee