Magic cluster ion distributions: (NO)3+(N2O)nand (NO)3+(CO2)n
โ Scribed by Sunil Desai; C. S. Feigerle; John C. Miller
- Publisher
- Springer
- Year
- 1993
- Tongue
- English
- Weight
- 375 KB
- Volume
- 26
- Category
- Article
- ISSN
- 1434-6060
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## Abstract For Abstract see ChemInform Abstract in Full Text.
The equilibrium constant, K,, of the reaction NO2 + NO3 + M N z O ~ + M has been determined for a small range of temperatures around room temperature in air at 740 torr by direct spectroscopical measurements of NOz, NOS, and NzOs. At 298 K, K, was determined as (3.73 2 0.61) x lo-'' cm3 molecule-'.
The gas-phase reaction of the NOa radical with NO, was investigated, using a flash photolysis-visible absorption technique, over the total pressure range 25-400 Torr of nitrogen or oxygen diluent a t 298 2 2 K. The absolute rate constants determined (in units of em3 molecule-' s-') a t 25, 100, and