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Madelung fields from optimized point charges for ab initio cluster model calculations on ionic systems

✍ Scribed by C. Sousa; J. Casanovas; J. Rubio; F. Illas


Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
481 KB
Volume
14
Category
Article
ISSN
0192-8651

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✦ Synopsis


A simple procedure devised to obtain optimized point charges to represent the Madelung potential is reported and applied to six different crystal structures occurring in ionic systems. Their use in ab initio cluster model calculations is discussed through some selected examples and results compared with those arising from the use of the well-known Evjen method.