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Macromolecular recognition: new cyclodextrin polyrotaxanes and molecular tubes

✍ Scribed by Akira Harada; Miyuko Okada; Yoshinori Kawaguchi; Mikiharu Kamachi

Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
304 KB
Volume
10
Category
Article
ISSN
1042-7147

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We found that many ␣-CDs are threaded on a poly(ethylene glycol) (PEG) chain to form a crystalline complex in high yields, although ␀-CD did not form complexes with PEG. It was made clear that the relationship between the chain cross-sectional areas of the polymers and the diameters of the cavities

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## Abstract Interaction of __Ξ²__‐cyclodextrin (__Ξ²__‐CD) with alternating copolymers (pAdMA and pAdPhMA) of sodium maleate with adamantyl (Ad) and with adamantylphenyl (AdPh) vinyl ether has been investigated by several NMR techniques. Comparing the apparent association constants (__K__) for the po